期刊
CHEMISTRY OF MATERIALS
卷 28, 期 2, 页码 556-563出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.5b04039
关键词
-
资金
- Department of Chemistry and Biochemistry at The Ohio State University
- U.S. Department of Energy (DOE) through the Clean Energy Research Center for Clean Vehicle Collaboration (CERC-CVC) [DE-PI0000012]
The viability of using aluminum (Al) foil as the anode current collector in Li-ion batteries was demonstrated using in situ neutron depth profiling (NDP). A 500 nm thin Sn film, physical vapor deposited onto an Al foil, was monitored using NDP during lithiation and subsequent delithiation. Results indicate exclusive lithiation of the Sn electrode throughout the 0.05 to 1.00 V vs Li/Li+ range, leaving the Al foil current collector unlithiated even at the low potentials sufficient to lithiate Al. Additionally, 60-80 nm Sn nanoparticles suspended in a polyvinylidine fluoride (PVDF) matrix were cast onto an Al foil current collector and lithiated under constant current (C/6 rate). Results indicate the preferential lithiation of Sn nanoparticles. At lithiation potentials >0.3 V, Al lithiation is avoided even when the current collector is in direct contact with the electrolyte solution.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据