期刊
CHEMISTRY OF HETEROCYCLIC COMPOUNDS
卷 52, 期 10, 页码 803-808出版社
SPRINGER
DOI: 10.1007/s10593-016-1969-5
关键词
amidines; 1H-benzo[f]chromenes; 4H-chromenes; guanidine; pyrimidines; aza-Michael reaction; cascade reactions
资金
- Ministry of Education and Science of the Russian Federation [14.574.21.0120, RFMEFI57414X0120]
A series of 2-[(pyrimidin-5-yl)methyl]phenols and 1-[(pyrimidin-5-yl)methyl]-2-naphthols have been accessed via the interaction of carbonyl-substituted 4H-chromenes and 1H-benzo[f]chromenes with amidines and guanidine in a reaction cascade initiated by the Michael reaction. It was established that in this transformation chromenes act as the synthetic equivalents of hydroxybenzylated alpha-formyl ketones or alpha-formylaldehydes.
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