期刊
CHEMISTRY LETTERS
卷 45, 期 10, 页码 1177-1179出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.160530
关键词
C-H bond functionalization; Olefination; Rhodium
资金
- ACT-C from Japan Science and Technology Agency (JST, Japan)
- Ministry of Education, Culture, Sports, Science and Technology (MEXT, Japan) [26102004, 25105714]
- Japan Society for the Promotion of Science (JSPS, Japan) [15H06201]
- Umicore
- Grants-in-Aid for Scientific Research [15H06201] Funding Source: KAKEN
The concise synthesis of a fungal metabolite, (+)-fusarochromanone (FC-101), was achieved via the oxidative sp(2) C-H bond olefination of an N-acetylaminochromanone with a chiral functionalized electron-rich alkene, catalyzed by an electron-deficient (eta(5)-cyclopentadienyl)rhodium(III) complex, [(CpRhCl2)-Rh-E](2), under ambient conditions as the key step. This protocol was applied to various acetanilides and functionalized electron-rich alkenes for the syntheses of fusarochromanone analogs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据