期刊
CHEMISTRY LETTERS
卷 45, 期 11, 页码 1274-1276出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.160649
关键词
Rotaxane catalyst; Asymmetric O-benzoylation; Cooperative effect
资金
- ACT-C program (JST)
- JSPS KAKENHI [16K17866]
- Naito Foundation
- Grants-in-Aid for Scientific Research [16K17866] Funding Source: KAKEN
A novel rotaxane-type asymmetric catalyst that displays its function through the cooperative effect of the components was designed and synthesized to evaluate its catalytic activity in the O-acylation of meso-1,2-diol. The catalyst efficiently catalyzed the selective monobenzoylation of meso-1,2-hydrobenzoin to afford both 99% yield and 98% ee. The cooperative working of the two components is essential for the excellent reactivity and enantioselectivity.
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