期刊
RECORDS OF NATURAL PRODUCTS
卷 14, 期 4, 页码 292-296出版社
ACG PUBLICATIONS
DOI: 10.25135/rnp.168.19.12.1505
关键词
Fusidic acid; Cunninghamella echinulata; 3-O-formylation
Minor metabolites of fusidic acid (1) using the fungus Cunninghamella echinulata NRRL 1382 were investigated for discovering previously unstudied reactions. An unprecedented fusidic acid derivative, 3-O-formyl-27-hydroxyfusidic acid (2) was isolated, and its chemical structure was fully elucidated using various spectroscopic techniques including 1D, 2D NMR and HRESIMS. This is the first report for formylation reaction by C. echinulata.
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