期刊
PLASMA PROCESSES AND POLYMERS
卷 17, 期 9, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ppap.202000069
关键词
gliding arc; hydrogen production; nonthermal plasma; water
资金
- National Natural Science Foundation of China [11975069]
- Fundamental Research Funds for the Central Universities [DUT20GJ211]
To disclose water roles in plasma reforming of methanol for hydrogen production, gliding arc discharge characteristics, optical emission spectra, and reaction behavior are investigated over a water concentration range of 0-95 mol%. It can be concluded that the varied reaction behavior with water concentration derives from three water roles as a homogeneous catalyst, CO oxidant, and side-product. The former two roles of water are beneficial for hydrogen production. The side-product role of water, accompanied by hydrocarbons formation, which is disadvantageous to hydrogen production and can be almost fully inhibited by the homogeneous catalysis of water at above 33 mol% H2O. As an oxidant, water conversion is controlled by the thermodynamic equilibrium at the gas temperature of arc.
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