期刊
PETROLEUM CHEMISTRY
卷 60, 期 4, 页码 479-489出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544120040180
关键词
hydroisomerization; n-hexadecane; mesoporous zeolites; MCM-41; MCM-48; KIT-6; diffusion
类别
资金
- Total S.A.
- ANRT
- Total
n-Hexadecane hydroconversion has been investigated in a series of bifunctionnal metal/acid catalysts featuring distinct well-defined pore architectures. The acidic components were prepared from dealuminated Y zeolites with Si/Al of 15 and 30 post treated in alkaline medium to generate ordered or non-ordered secondary networks of mesopores and from aluminated ordered mesoporous materials MCM-41, MCM-48, KIT-6 type materials and amorphous silica gel. Activity relates linearly to the strength and number of strong Bronsted acid sites, while selectivity, more precisely the yield in isomerization products, scales directly with the mesopore volume of the catalyst. The architecture of the mesoporous network, namely the ordering, interconnectivity, homogeneity of the mesopores, affects little catalytst behavior. Confrontation of catalytic data with diffusion measurements suggests the existence of an optimal mesopore size above which the number of strong Bronsted sites and the mesopore volume are the only parameters governing catalytic performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据