期刊
ORGANIC LETTERS
卷 22, 期 9, 页码 3642-3648出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01144
关键词
-
资金
- SERB New Delhi [ECR/2018/000003]
- DAE
- NISER
- UGC
Selective and efficient hydrosilylations of esters to alcohols by a well-defined manganese(I) complex with a commercially available bisphosphine ligand are described. These reactions are easy alternatives for stoichiometric hydride reduction or hydrogenation, and employing cheap, abundant, and nonprecious metal is attractive. The hydrosilylations were performed at 100 degrees C under solvent-free conditions with low catalyst loading. A large variety of aromatic, aliphatic, and cyclic esters bearing different functional groups were selectively converted into the corresponding alcohols in good yields.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据