期刊
ORGANIC LETTERS
卷 22, 期 10, 页码 3979-3984出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01288
关键词
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资金
- Spanish Agencia Estatal de Investigacion
- European Regional Development Fund [PGC2018-095025-B-I00, CTQ2016-78205-P, CTQ2016-81797-REDC]
alpha,beta-Unsaturated alpha'-alkoxy ketones have been prepared under mild conditions from allenes using water as the oxygen source and without the necessity of metals. The organocatalytic oxygenation-rearrangement sequence displays an exquisite chemo-, stereo-, and site-selectivity as well as good functional group compatibility. DFT calculations suggest that stabilizing noncovalent Se center dot center dot center dot O interactions may be responsible for the observed reactivity.
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