4.8 Article

Visible-Light-Induced Palladium-Catalyzed Intermolecular Narasaka-Heck Reaction at Room Temperature

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ORGANIC LETTERS
卷 22, 期 10, 页码 3964-3968

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01267

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资金

  1. National Natural Science Foundation of China [21672047]
  2. State Key Laboratory of Urban Water Resource and Environment [2018DX02]
  3. Science and Technology Plan of Shenzhen [JCYJ20180306171926120]
  4. Harbin Institute of Technology (Shenzhen) through the Talent Development Starting Fund from Shenzhen Government

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A palladium-catalyzed Narasaka-Heck reaction by a domino cross-coupling reaction with aromatic alkenes under blue LED irradiation at room temperature was developed. The undesired beta-hydride elimination of the hybrid alkyl palladium radical species was prohibited, enabling a broad range of oxime esters to undergo 5-exo cyclization and subsequent coupling with olefins. The practicality of the method was well illustrated by the construction of a nitrogen bridgehead tricycle as a core skeleton of alkaloids.

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