期刊
ORGANIC LETTERS
卷 22, 期 7, 页码 2791-2796出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c00768
关键词
-
资金
- Knut och Alice Wallenbergs Foundation [2018.0066]
- Carl Trygger Foundation
A one-pot approach to fluorinated hydroxamic acid, amide, and thioamide derivatives is reported. The reaction proceeds via an N-perfluoroalkylation of nitrosoarenes with perfluoroalkanesulfinates, resulting in labile N-perfluoroalkylated hydroxylamines. By the addition of suitable additives, a controllable oxy/thiodefluorination of the fluorinated hydroxylamine intermediates was achieved. The method highlights N-perfluoroalkylated amines as versatile intermediates for further synthesis.
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