期刊
ORGANIC LETTERS
卷 22, 期 9, 页码 3581-3585出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01024
关键词
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资金
- National Key Research and Development Program [2016YFA0200302]
- Shanghai Municipal Science and Technology Major Project [2018SHZDZX03]
- National Nature Science Foundation of China (NSFC) [21772039, 21472213]
- Croucher Foundation (Hong Kong)
- Fundamental Research Funds for the Central Universities
- Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
An unprecedented approach of metal-free C(sp(2))-N bond formation via deacetylation/intramolecular aryl migration is demonstrated with novel N-sulfonamide substituted diaryliodonium salts. The reaction provides a variety of ortho-iodo N-aryl sulfonamides. The products were employed in several coupling reactions to afford useful diarylamine scaffolds. Furthermore, the key intermediates of zwitterionic iodoniums in the reaction were isolated and verified by the X-ray crystallographic analysis, which showcased unambiguous mechanistic insight into the reactivity of the reaction cascade.
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