期刊
CHEMICAL REVIEWS
卷 116, 期 19, 页码 12466-12535出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.6b00346
关键词
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资金
- BASF SE (Ludwigshafen, Germany)
- U.S. Department of Defense
- Defense Threat Reduction Agency [HDTRA 1-12-10053]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Energy Frontier Research Center [DE-SC0001015]
- US National Science Foundation [DMR 1104798]
- National Basic Research Program of China (973 Program) [2012CB821706, 2013CB834803]
- National Natural Science Foundation of China [91222202, 21171114]
- German Research Foundation (DFG) [SCHO 1639/1-1]
Rod MOFs are metal organic frameworks in which the metal-containing secondary building units consist of infinite rods of linked metal-centered polyhedra. For such materials, we identify the points of extension, often atoms, which define the interface between the organic and inorganic components of the structure. The pattern of points of extension defines a shape such as a helix, ladder, helical ribbon, or cylinder tiling. The linkage of these shapes into a three-dimensional framework in turn defines a net characteristic of the original structure. Some scores of rod MOF structures are illustrated and deconstructed into their underlying nets in this way. Crystallographic data for all nets in their maximum symmetry embeddings are provided.
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