期刊
CHEMICAL REVIEWS
卷 116, 期 22, 页码 13752-13990出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.6b00354
关键词
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资金
- JSPS KAKENHI [25220804]
- Grants-in-Aid for Scientific Research [16K17892, 16H01016] Funding Source: KAKEN
In this review, we describe the recent advances in supramolecular helical assemblies formed from chiral and achiral small molecules, oligomers (foldamers), and helical and nonhelical polymers from the viewpoints of their formations with unique chiral phenomena, such as amplification of chirality during the dynamic helically assembled processes, properties, and specific functionalities, some of which have not been observed in or achieved by biological systems. In addition, a brief historical overview of the helical assemblies of small molecules and remarkable progress in the synthesis of single-stranded and multistranded helical foldamers and polymers, their properties, structures, and functions, mainly since 2009, will also be described.
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