期刊
NANO RESEARCH
卷 14, 期 2, 页码 507-511出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-020-2713-0
关键词
metal-organic frameworks (MOFs); gas storage; methane; hydrogen; carbon dioxide
类别
资金
- National Natural Science Foundation of China [21971038, 21975044, 21805039, 21673039, 573042]
- Fujian Science and Technology Department [2019H6012, 2018J07001]
- China Postdoctoral Science Foundation [2018M642556]
- Welch Foundation [AX-1730]
BUT-22 is a microporous aluminum-based MOF with high storage capacities for methane, hydrogen, and carbon dioxide, showing excellent performance under different conditions.
We report a microporous aluminum-based metal-organic framework (MOF), BUT-22 for high methane (CH4), hydrogen (H-2), and carbon dioxide (CO2) storage. At 296 K and 80 bar, BUT-22 exhibits a high gravimetric CH(4)storage capacity of 530 cm(3)(STP)/g (0.379 g/g). BUT-22 also has a high gravimetric H(2)storage capacity of 12 wt.% at 100 bar and 77 K. In addition, the CO(2)adsorption studies revealed that BUT-22 exhibits a high absolute gravimetric CO(2)uptake of 1.7 g/g at 296 K and 40 bar.
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