期刊
NANO LETTERS
卷 20, 期 7, 页码 5141-5148出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.0c01364
关键词
2D lead halide perovskites; exciton fine-structure; electron-hole exchange interaction; spin mixing
类别
资金
- Singapore National Research Foundation through the NRF Investigatorship Award [NRF-NRFI2015-03]
- Singapore Ministry of Education [MOE2018-T3-1-002, MOE2018T2-2-068, RG103/15, RG113/16]
- Singapore National Research Foundation through a Singapore 2015 NRF fellowship Grant [NRF-NRFF2015-03]
- MOST of China [2017YFA0303400]
- NSFC [11434010]
- HFML-RU/FOM, a member of the European Magnetic Field Laboratory (EMFL)
- Nanyang Technological University
The fast-growing field of atomically thin semiconductors urges a new understanding of two-dimensional excitons, which entirely determine their optical responses. Here, taking layered lead halide perovskites as an example of unconventional two-dimensional semiconductors, by means of versatile optical spectroscopy measurements, we resolve fine-structure splitting of bright excitons of up to similar to 2 meV, which is among the largest values in two-dimensional semiconducting systems. The large fine-structure splitting is attributed to the strong electron-hole exchange interaction in layered perovskites, which is proven by the optical emission in high magnetic fields of up to 30 T. Furthermore, we determine the g-factors for these bright excitons as similar to+1.8. Our findings suggest layered lead halide perovskites are an ideal platform for studying exciton spin-physics in atomically thin semiconductors that will pave the way toward exciton manipulation for novel device applications.
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