期刊
MOLECULES
卷 25, 期 7, 页码 -出版社
MDPI
DOI: 10.3390/molecules25071527
关键词
esterification; amination; DDQ; diarylmethanes; benzyl ester
资金
- Normal Project Foundation of Hunan Provincial Education Department [18C0845]
- Key Project Foundation of Hunan Provincial Education Department [18A396, 19A085]
- Natural Science Foundation of Hunan Province [2017JJ2018]
An esterification and amination of benzylic C-H bonds was developed by using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) under metal- and iodide-free conditions. Both carboxylic acids and amines could be used as ideal coupling partners for the oxidative coupling reactions with various diarylmethanes. A close to equal amount of coupling reagents was enough to afford the product in good to high yields.
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