期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 296, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2020.110001
关键词
Spherical mesoporous SBA-15; Long rod-like mesoporous SBA-15; Hexagonal prism-like mesoporous SBA-15; Silicon nanoparticles; Oxygen sensing
类别
资金
- National Natural Science Foundations of China [21671070]
- GDUPS
- Project for Construction of High-level University in Guangdong Province of China
- Guangzhou Science & Technology Project, China [201707010033]
- Special Funds for the Cultivation of Guangdong College Students' Scientific and Technological Innovation [201910564035]
In this paper, our effort is focused on preparation and oxygen sensing of fluorescent silicon nanoparticles (Si NPs) assembled in three kinds of mesoporous SBA-15 with different morphologies, including spherical mesoporous SBA-15 (SPSBA-15), long rod-like mesoporous SBA-15 (LRSBA-15) and hexagonal prism-like mesoporous SBA-15 (HPSBA-15). The relationship of structure and sensing properties in mesoporous materials is studied. Small angle powder X-ray diffraction (SAXRD), Fourier transform infrared spectrometer (FT-IR), Brunauer-Emmett-Teller (BET), Discrete-Fourier-Transform (DFT) analyses and X-ray photoelectron spectroscopy (XPS) are used to characterize their structural properties. The obtained mesoporous SPSBA-15, LRSBA-15 and HPSBA-15 possess abundant Si-O-Si bands of the inorganic framework and high surface-volume ratios. Particularly, mesoporous HPSBA-15 materials exhibit the largest surface areas than other two mesoporous materials. Accordingly, the adding volume of Si NPs was 8 ml in mesoporous HPSBA-15. At the same time, the hybrid materials show the shortest response time of 2.2 s and recovery time of 11.2 s. This result can be attributed to the uniform and nearly parallel porous structure of the HPSBA-15 materials supporting with large surface areas and narrow pore size distributions. Therefore, the properties in oxygen sensing can be improved by using mesoporous SBA-15 materials with larger BET surface area.
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