期刊
MENDELEEV COMMUNICATIONS
卷 30, 期 2, 页码 162-164出版社
ELSEVIER
DOI: 10.1016/j.mencom.2020.03.010
关键词
pyrazine-fused dimers; porphyrins; diamines; oxidation; nickel complexes; panchromatic absorption
资金
- Russian Foundation for Basic Research [19-33-70036]
- Council of the President of Russian Federation [MK-1454.2019.3]
New pyrazine-fused porphyrin dimer was unexpectedly produced by mild oxidation of [2,3-diamino-5,10,15,20-tetrakis(4-butoxyphenyl)porphyrinato]nickel(ii) in 40% yield. The obtained porphyrin dimer demonstrates bathochromic shift of absorption bands compared to the reported analogues, along with panchromatic absorption in the 250-650 nm range, which is promising for optical, photovoltaic and medical applications.
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