期刊
MACROMOLECULES
卷 53, 期 8, 页码 2942-2949出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.0c00157
关键词
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资金
- JSPS KAKENHI [JP15H05477, JP15K05513, JP16K13953]
- Ibaraki University Priority Research Grant
- Shorai Foundation for Science and Technology
- Shin-sozai Joho Zaidan
- Eno Scientific Foundation
- ICR-JURC, Kyoto University [2018-105, 2019-121]
A polycondensation of 1,4-dimethoxy-2,5-bis(trifluorovinyl)benzene (1) with bisphenols in the presence of K2CO3 afforded aromatic polymers 3 consisting of both the (E)- and (Z)-Ar-CF=CF-O-Ar' moieties in the main chains. The M-n and M-w values of polymer 3c prepared from bisphenol-AF were up to 6.62 x 10(4) and 1.29 X 10(5), respectively. The polymers 3 were transparent in the visible region (>400 nm) and exhibited good thermal stability (T-d5% > 320 degrees C). Fluorescence spectroscopy and X-ray diffraction analysis indicated the amorphous character of polymer 3c. The drop-cast film of 3c showed that the refractive indices and Abbe's number were comparable to those for widely used polymers having optical applications, such as polycarbonate and polystyrene.
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