期刊
CHEMICAL ENGINEERING JOURNAL
卷 286, 期 -, 页码 329-338出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2015.10.073
关键词
Sorption enhanced reforming; Glycerol; Hydrogen production; Bi-functional catalyst; Mayenite; Calcium cobaltate
资金
- National Natural Science Foundation of China [20176094]
- Program for New Century Excellent Talents in University [NCET-12-0190]
- Guangdong Provincial Natural Science Foundation [S20120011275, 2014A030312007]
- Pearl River Nova Program of Guangzhou City [2011J2200062]
- Fundamental Research Funds for the Central Universities of China [2014ZG0005, 2015PT012]
Sorption enhanced steam reforming of glycerol (SESRG) enables the production of high-purity hydrogen from the by-product of biodiesel manufacture. To this end, highly stable catalysts and CO2 sorbents are desired to overcome the performance degradation at high temperatures. Herein, a hi-functional catalyst, Co-CaO-Ca12Al14O33, is proposed to couple CO2 sorption and catalytic reforming of glycerol on nanoscale. The catalyst was derived from a Co-Ca-Al hydrotalcite-like (HTl) material to achieve homogeneous mixing of Co, CaO and Ca12Al14O33 as a spacer to prevent CaO sintering. At Ca/Al of 2.8, the highest catalytic activity and sorption capability were reached. Over the optimized catalyst, high-purity H-2 of 96.4% was produced at 525 degrees C through SESRG during the pre-breakthrough stage. High stability of the hi-functional catalyst was demonstrated by a cyclic SESRG-calcination operation up to 50 times. The role of Ca12Al14O33 as spacer of CaO was proved by XRD and TEM-EDS analysis. In addition, it was found that Ca3CO2O6, which is formed during the calcination stage and is reduced during the SESRG to release Co catalysts, may act as a dynamic reservoir of Co catalysts to prevent Co from sintering, leading to an excellent SESRG activity and stability. (C) 2015 Elsevier B.V. All rights reserved.
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