期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 40, 期 54, 页码 1989-1998出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2020.01.004
关键词
Mechanical properties; Creep; Lanthanum silicate; SOFC electrolyte; Grain; Boundary sliding
资金
- University Paris-Saclay (IDEX 2014)
- Centre National de la Recherche Scientifique (Program Instrumentation aux limites)
- University of Sevilla (VI PPIT-US)
- Spanish Ministerio de Ciencia, Innovacion y Universidades [MAT2016-76526-R]
High density La9.33Si6O26 polycrystals were fabricated by conventional and spark plasma sintering starting from nanopowders synthesized by freeze-drying. The materials exhibit a homogeneous microstructure formed by equiaxed grains with average sizes of 1.1 mu m and 0.2 mu m-diameter depending on the sintering route. Compressive mechanical tests were performed in air at constant strain rate between 900 and 1300 degrees C. A gradual brittle-to-ductile transition was found with increasing temperature and/or decreasing strain rate. Grain boundary sliding is the main deformation mechanism in the ductile region, characterized by a stress exponent n = 1 for the conventional sintered (large-grained) material and n = 2 for the spark plasma sintered (fine-grained) material; in both cases, the activation energy for creep was 360 kJ/mol. Effective cation diffusivities have been derived from mechanical data by comparison with appropriate models. The creep properties of lanthanum silicates are reported here for the first time.
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