Highly efficient Pd-doped ferrite spinel catalysts for the selective catalytic reduction of NO with H2 at low temperature

Palladium-doped ferrite spinels with various divalent metals (Co, Cu or Zn) were prepared using the sol-gel auto-ignition method for use in the selective catalytic reduction of NO with hydrogen (H-2-SCR). The activity of the Co-FePd catalyst was greatly enhanced by adding a small amount of palladium and resulted in approximately 96% NO conversion in the 170-250 degrees C range. In TPD and TPR analyses, Co-FePd exhibited a larger peak area and a lower reductive temperature than the other studied materials, indicating that this catalyst possesses stronger reduction ability and larger acidity; these properties were very important for the catalytic performance of Co-FePd, which showed the best SCR activity of the tested materials. The catalytic activities ranked in the following order: Co-FePd > Zn-FePd > Cu-FePd. Adding H2O to the reacting gas mixture slightly decreased NO conversion by the Co-FePd oxide. When the H2O content was increased from 3% to 5%, no further decline of NO conversion occurred. The presence of 100 ppm SO2 in the gas phase decreased the SCR activity of Co-FePd by approximately 19%, but no further deactivation was observed when the concentration was increased to 150 ppm. When SO2 was removed from the feed stream, NO conversion recovered rapidly; however, the conversion was not restored to the original level, indicating that SO2 has both a reversible and an irreversible effect on the H-2-SCR reaction. (C) 2016 Elsevier B.V. All rights reserved.