期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 48, 页码 7580-7583出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01120a
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资金
- New York State Energy Research Development Authority [NYSERDA] [18500]
- U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-98CH10886]
The electrochemical behaviour of tetrathiafulvalene (TTF), a redox mediator proposed to improve the recharge kinetics of Li-O-2 batteries, was investigated via synchrotron and lab X-ray diffraction. Using the LiFePO4 anode, TTF causes chemical lithiation of the FePO4 phase. TTF is also found to be unstable during discharge/charge cycles.
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