期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 9, 页码 1915-1918出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07879b
关键词
-
资金
- National Basic Research Program of China [2015CB856600]
- NSFC [21572201, 21422206, 21272206]
Herein we report a Pd-catalyzed alkylation of lactic acid with the assistance of 8-aminoquinoline auxiliary. A wide range of alkyl iodides bearing beta-hydrogen atoms are compatible with the reaction conditions, providing a practical and straightforward alternative to access chiral alpha-hydroxy acids (AHAs). The new reactions have been applied for the synthesis of isotope-labeled AHAs and a sugar-containing complex AHA.
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