期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 12, 页码 8157-8165出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c01081
关键词
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资金
- Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture [XTE1826]
- Natural Science Research Projects of Jiangsu Higher Education [19KJB150027]
The NH4I-triggered formal [4 + 2] annulation of alpha,beta-unsaturated ketoxime acetates with N-acetyl enamides has been developed. The current protocol employs electron-rich enamides as C2 synthons and enables the efficient and straightforward construction of polysubstituted pyridines in moderate to good yields based on metal-free systems. The reaction tolerates a wide range of functional groups and represents an alternate route toward the synthesis of pyridine derivatives.
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