期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 12, 页码 8271-8278出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00910
关键词
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资金
- JSPS KAKENHI [JP18H04615]
- AMED [JP18gm1010007, JP18ak0101072]
- Uehara Memorial Foundation
A total synthesis of polyoxamic acid has been achieved. The key feature of the synthetic route is a visible-light-mediated beta-scission and carbon-to-carbon 1,5-hydrogen atom transfer (1,5-HAT) to provide the functionalized alditol under mild conditions. This type of carbon-to-carbon 1,5-HAT initiated by C(sp(3))-centered radicals has been scarcely reported. Furthermore, the reaction was adapted for flow chemistry, facilitating the total synthesis of polyoxamic acid.
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