期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 11, 页码 7526-7533出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00640
关键词
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资金
- Marubun Research Promotion Foundation
Acyl fluorides are subjected to methoxylation with tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) to afford the corresponding methyl esters in good to excellent yields. This transformation is featured by C(sp(2))-OMe bond cleavage under metal-free conditions. Unprecedented utilization of TMPP as a methoxylating agent realized the installation of an OMe group into the desired products.
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