期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 11, 页码 7515-7525出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00250
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资金
- National Natural Science Foundation of China [21971201]
- Natural Science Basic Research Plan in Shaanxi Province of China [2019JM299]
- Key Laboratory Construction Program of Xi'an Municipal Bureau of Science and Technology [201805056ZD7CG40]
A nickel-catalyzed Suzuki alkyl-aryl coupling of cycloalkyl silyl peroxides with boronic acids is reported. The primary and secondary ketoalkyl electrophiles generated through C-C bond cleavage were amenable, providing rapid access to a variety of distal arylated alkyl ketones. A radical pathway is proposed for this reaction.
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