期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 8, 页码 5362-5369出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00055
关键词
-
资金
- Japan Society for the Promotion of Science (JSPS) [17K05779]
- Grants-in-Aid for Scientific Research [17K05779] Funding Source: KAKEN
Photoinduced decarboxylative radical reactions of benzoic acids with electron-deficient alkenes, diborane, and acetonitrile under organic photoredox catalysis conditions and mild heating afforded adducts, arylboronate esters, and the reduction product, respectively. The reaction is thought to involve single-electron transfer promoted the generation of aryl radicals via decarboxylation. A diverse range of benzoic acids were found to be suitable substrates for this photoreaction. Only our two-molecule organic photoredox system can work well for the direct photoinduced decarboxylation of benzoic acids.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据