期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 24, 页码 4418-4445出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10447e
关键词
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资金
- Natural Science Foundation of China [21571016, 91122028, 21571048, 21301049, U1304208, 20725101]
- 973 Program [2014CB932101]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [16HASTIT001]
- Natural Science Foundation of Henan Province [142300410451]
- Postdoctoral Foundation of Henan Province [2014025]
- Special Foundation for Scientific Research Project of Henan University [XXJC20140001]
- Young Backbone Teachers Foundation from Henan Province [2012GGJS-027]
- Students Innovative Pilot Plan of Henan University [15NA002]
With the rapid development of science and technology and the trend of multidisciplinary pervasion, POM-based TM-RE heterometallic chemistry (POM = polyoxometalate, TM = transition-metal, RE = rare-earth) has become one of the most rapidly growing and challengeable areas of inorganic chemistry due to the impressive structural diversities, various chemical compositions and potential applications of these materials in magnetism, optics, electrochemistry, electrocatalysis and materials science. Over the past several years, continuous interest and persisting efforts have been dedicated to the preparation and exploration of POM-based TM-RE heterometallic derived materials (PTRHDMs), which have led to more than two hundred PTRHDMs. In this review, we summarize the structural types of reported PTRHDMs together with synthetic strategies, structural motifs and relevant functional applications. The exciting array of this emerging research theme presages continuous growth and great vitality. In the last section, some prospects of this branch are also presented and possible guidance for future work is outlined.
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