期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 93, 页码 13564-13567出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06427b
关键词
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资金
- NSFC [21671122, 21475078, 21271120, 21604049]
- Shandong Provincial Natural Science Foundation, China [BS2015CL015]
- Project of Shandong Province Higher Educational Science and Technology Program [J15LC05]
A UiO-66-MOF-based membrane UiO-66-TEM (1) was prepared by the assembly of methacrylamide-decorated UiO-66-NH-Met with a thiol side chain-attached polysiloxane (PSI-SH) via a photoinduced thiol-ene click reaction. The obtained membrane 1 can be a platform to support Au nanoparticles (Au NPs) to generate an Au-MOF-polymer composite membrane Au@UiO-66-TEM (2). 1 and 2 can be used to build highly efficient continuous flow-through membrane reactors for Knoevenagel condensation of 4-nitrobenzaldehyde with malononitrile and 4-nitrophenol (4-NP) reduction at ambient temperature, respectively.
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