期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 39, 页码 6545-6548出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01234e
关键词
-
资金
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21133011, 21373246, 21522309]
An unprecedented catalyst-free formylation of amines using CO2 and hydrosilanes was developed. The solvent plays a vital role in promoting the interaction of amines with hydrosilanes and subsequent CO2 insertion, thus facilitating the simultaneous activation of N-H and Si-H bonds. Based on relevant mechanistic studies, a plausible mechanism involving a silyl carbamate intermediate is proposed.
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