期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 20, 期 3, 页码 1790-1798出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2020.17175
关键词
Tungsten Oxide; Microflowers; Hydrothermal Process; NO2
类别
资金
- National Natural Science Foundation of China [11774241, 51872187, 61704111, 61504083, 51371120]
- Natural Science Foundation of Guangdong province [2017A030310524]
- Public welfare capacity building in Guangdong Province [2015A010103016]
- Project of Department of Education of Guangdong Province [2014KTSCX110]
- Science and Technology Foundation of Shenzhen [JCYJ20180507182248925, JCYJ20160226192033020]
- National Key Research and Development Program of China [2017YFB0404100, 2017YFB0403000]
- Science and Technology Foundation of Shenzhen
Tungsten oxide microflowers (WO3 MFs) were fabricated by a simple hydrothermal process through adjusting the pH of the solution by HCl. These MFs possess the outer diameters of about 2 mu m and are composed of numerous nanoplates with the average pore size of 10.9 nm. Chemiresistive activity of as-fabricated WO3 MFs sensor was attempted towards oxidizing and reducing target gases, revealing a superior selectivity to NO2 with a maximum response of 22.95 (2 ppm NO2) @ 105 degrees C compared to other target gases. One of the key features of as-fabricated WO3 MFs sensor is the lower detection limit of 125 ppb and operating temperature of 105 degrees C to NO2 with better reproducibility, signifying commercial prospective of the developed sensor materials. Finally, the gas sensing mechanism of WO3 MFs sensor has been proposed.
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