期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 44, 页码 7138-7141出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03106d
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资金
- National Science Foundation [CHE-1465142]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1465142] Funding Source: National Science Foundation
A new method for intramolecular C-H oxidative amination is based on a FeCl3-mediated oxidative reaction of anilines with activated sp(3) C-H bonds. The amino group plays multiple roles in the reaction cascade: (1) as the activating group in single-electron-transfer (SET) oxidation process, (2) as a directing group in benzylic/allylic C-H activation at a remote position, and (3) internal nucleophile trapping reactive intermediates formed from the C-H activation steps. These multielectron oxidation reactions proceed with catalytic amounts of Fe(III) and inexpensive reagents.
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