期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1205, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2019.127608
关键词
Direct arylation; 2-iso-propylthiazole; 2-n-butylfuran; 2-n-butylthiophene; Pd-PEPPSI complexes; X-ray diffraction
资金
- Inonu University (Turkey) Research Fund [IUBAP: 2016/109]
- Dokuz Eylul University [2010.KB.FEN.13]
The prestige of the PEPPSI (Pyridine-Enhanced Precatalyst Preparation Stabilization and Initiation) complexes in organometallic chemistry is increasing day by day. Herein, the well-defined seven meta-cyanobenzyl-substituted N-heterocyclic carbene (NHC)-Pd(II)-pyridine (Pd-PEPPSI) complexes were synthesized using palladium acetate, which unlike general procedure is a more economical method than palladium chloride. The new Pd-PEPPSI complexes were obtained from the reaction of the cyanobenzyl substituted NHC precursors and palladium acetate in pyridine. The new complexes have been fully characterized by H-1 NMR, C-13 NMR, FTIR spectroscopy and elemental analysis techniques. Also, the X-ray diffraction method was used to determine the single-crystal structure of a complex. The Pd-PEPPSI complexes have been examined as catalysts in the direct arylation reactions of 2-n-butylfuran and 2-n-butylthiophene with aryl bromide. All complexes have demonstrated excellent activity in these reactions. The Molecular and crystal structure of one of the cyanobenzyl substituted Pd-PEPPSI complexes was determined by the single-crystal X-ray diffraction method. X-ray diffraction studies show that the molecular structure adopts a slightly distorted square-planar geometry with the palladium (II) center. (c) 2019 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据