期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 34, 页码 5876-5879出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01398h
关键词
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资金
- JSPS [15H03810]
- Grants-in-Aid for Scientific Research [15J01245, 15H03810] Funding Source: KAKEN
A cationic iridium/binap catalyst enabled the asymmetric [3+2] annulation of cyclic N-acyl ketimines with internal alkynes via C-H activation to give spiroaminoindene derivatives with high enantioselectivity. The stereochemical course of this annulation was switchable by acid additives.
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