4.7 Article

Continuous catalytic upgrading of ethanol to n-butanol over Cu-CeO2/AC catalysts

期刊

CHEMICAL COMMUNICATIONS
卷 52, 期 95, 页码 13749-13752

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05860d

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资金

  1. National Natural Science Foundation of China (NSFC) [21303163]
  2. Natural Science Foundation of Zhejiang Province [LY13B030006, LY17B060006]
  3. Qianjiang Talent Project in Zhejiang Province [QJD1302011]
  4. Scientific Research Fund of Zhejiang Provincial Education Department [Y201328681]

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Cu-CeO2/AC catalysts exhibited extraordinary catalytic performance in the upgradation of ethanol to n-butanol. To the best of our knowledge, this is the first report that the highest n-butanol yields of 21.6% and nearly 20% could be achieved over heterogeneous catalysts under mild reaction conditions in batch and fixed-bed reactors, respectively. The high catalytic activity, selectivity and stability of these catalysts could be ascribed to the synergy of Cu, CeO2 and the activated carbon support.

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