期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 99, 页码 14298-14301出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07825g
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资金
- U.S. National Science Foundation [DMREF-0903225]
- Direct For Mathematical & Physical Scien [1434486] Funding Source: National Science Foundation
The catalytic potential of atomically precise quantum-sized gold nanoclusters (Au-38(SC2H4Ph)(24)) is explored for the three-component coupling of an aldehyde, an alkyne and an amine to synthesize propargylamines. A high catalytic efficiency with a very low loading (0.01 mol%) is achieved. Furthermore, the synergistic effect of the electron-deficient surface (i.e. Au delta+, 0 < delta(+) < 1) and the electronrich Au-23 core of the ligand-protected nanoclusters is critical for this catalytic reaction.
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