期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 75, 页码 11300-11303出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05930a
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资金
- National Natural Science Foundation of China [21372017, 21290183, 21572008]
- State Key Laboratory of Bioorganic and Natural Products Chemistry
The enantioselective total synthesis of the 3,4-fused indole alkaloid ht-13-A has been achieved. The synthesis features a zinc-mediated propargylation, a rhodium-catalyzed intramolecular C-H activation reaction, and a methylamine-mediated cyclization. This concise and efficient synthetic approach can be applied for the gram-scale synthesis of ht-13-A.
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