期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 53, 页码 8215-8218出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03015g
关键词
-
资金
- Australian Research Council DECRA fellowship
- INSA [IISER-P/GAP-142/7/2014]
pi-Complexation triggered Lewis acid-base interactions between open metal sites (OMS) of metal-organic frameworks (MOFs), and pi-e(-) rich adsorptive benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation.
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