期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 80, 页码 11885-11888出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06031e
关键词
-
资金
- Herbert C. Brown Center for Borane Research
The first general open-flask synthesis of amine-boranes with inexpensive and readily available reagents, such as sodium borohydride, sodium bicarbonate, water, and the desired amines is described. Even amines bearing borane-reactive functionalities, such as alkene, alkyne, hydroxyl, thiol, ester, amide, nitrile, and nitro are well tolerated. Some of these novel amine-boranes represent stable molecules containing potentially incompatible electrophilic and nucleophilic centers in proximity. This convenient scalable synthesis provides a novel class of organic ligands for surface functionalization, as demonstrated by the formation of self-assembled layers of thiol- and alkoxysilane-bearing amine-boranes on gold and silica surfaces, respectively.
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