期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 53, 页码 8251-8254出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02494g
关键词
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资金
- Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office [DE-AC02-05CH11231]
- NSF Graduate Research Fellowship Program
- U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office [DE-AC36-08GO28308]
One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules-specifically hydrogen, methane, or carbon dioxide.
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