期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 37, 页码 6324-6327出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02776h
关键词
-
资金
- National Natural Science Foundation of China [21421091, 21372244, 21572256]
A gold-catalyzed regioselective [3+2] cycloaddition of ynamides with 1,4,2-dioxazoles was developed and offers a novel approach to obtain highly functionalized oxazoles under mild reaction conditions. 1,4,2-Dioxazole was found to act as an efficient N-acyl nitrene equivalent to trigger a facile generation of alpha-imino gold-carbene intermediate through the elimination of a ketone.
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