期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 93, 页码 13604-13607出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07982b
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资金
- MEXT (Japan)
- Tokyo Ohka Foundation
- Grants-in-Aid for Scientific Research [26410117, 16J05331] Funding Source: KAKEN
The catalytic enantioselective Mannich-type reaction of dichloroacetonitrile with imines has been developed. Good yields and enantioselectivity were observed for the reaction with various imines using chiral bis(imidazoline) catalysts. beta-Aminonitriles or beta-aminoamide were obtained from products without the loss of enantiopurity.
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