4.7 Article

Stability of metal-organic frameworks under gamma irradiation

期刊

CHEMICAL COMMUNICATIONS
卷 52, 期 84, 页码 12502-12505

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06878b

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资金

  1. French National Research Agency (ANR) through the PIA (Programme d'Investissements d'Avenir) [ANR-11-RSNR-0013-01]
  2. Chevreul Institute [FR 2638]
  3. CNRS
  4. Ministere de l'Enseignement Superieur de la Recherche
  5. Region Hauts-de-France
  6. FEDER

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We report the study of the resistance of archetypal MOFs (MILs, HKUST-1, UiO-66, and ZIF-8) under gamma irradiation. The different porous solids were irradiated with doses up to 1.75 MGy. All the MOFs constructed with transition metals (Cu2+, Zn2+, Zr4+) exhibit an evident destruction of the framework, whereas the compounds constructed with aluminium remain intact.

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