期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 26, 页码 4768-4771出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01130f
关键词
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资金
- CNRS
- UPS-Toulouse
- INSA
- EU (ERC Advanced Grant, NANOSONWINGS) [2009-246763]
- Deutsche Forschungsgemeinschaft (Synergetic effects in chemistry) [SFB 858]
The synthesis and catalytic activity of long-chain NHC-stabilized RuNPs are presented. Full characterization of these novel nanostructures including surface state studies show that the ligand influences the number and the location of Ru active sites which impacts the NP catalytic activity, especially in hydrogenation reactions. The high stability and versatility of these nanosystems make them successful catalysts for both oxidation and hydrogenation reactions that can even be performed successively in a one pot-fashion.
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