期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 66, 页码 10163-10166出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05078f
关键词
-
资金
- Leverhulme Trust [RPG-2014-345]
A dual visible light photoredox and gold-catalysed C(sp(2))-C(sp(2)) cross coupling is described. The success of this mild, oxidant-and base-free cross coupling is highly dependent on the amount of water added. Mechanistic studies show two distinct pathways depending on the gold catalyst employed: transmetallation of the arylboronic acid with gold(I) occurs prior to oxidation of gold(I) to gold(III) using cationic gold(I) catalysts, whereas oxidation of gold(I) to gold(III) precedes transmetallation using neutral gold(I) catalysts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据