期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 43, 页码 6977-6980出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00390g
关键词
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资金
- Ministero dell'Istruzione, Universita e della Ricerca (MIUR-PRIN) [2008CSNZFR]
- Ministero dell'Istruzione, Universita e Ricerca [2010N3T9M4]
- University of Trieste (FRA)
- COST Action [CM1104]
A thiophene-based donor-acceptor phenothiazine dye has been functionalized with a peripheral glucose unit (PTZ-GLU) to bust its affinity to water and enhance dye-sensitized photogeneration of hydrogen. Compared to the corresponding alkyl derivative (PTZ-ALK), as well as the common hydrophilic triethylene glycol substitution (PTZ-TEG), the sugar derivative shows a lower contact angle; PTZ-GLU performed twice more efficient than PTZ-TEG in the photogeneration of hydrogen in terms of evolved gas and turnover number.
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