期刊
CHEMICAL COMMUNICATIONS
卷 52, 期 90, 页码 13229-13232出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07111b
关键词
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Natural products are privileged scaffolds due to their high propensity to possess bioactivity. To expedite discovery of thiol-containing compounds, we devised a selective solid-supported reagent for their immobilization, followed by cleavage of a photocleavable linker to yield stable natural product conjugates for direct detection by mass spectrometry. Importantly, the natural products can also be tracelessly released to yield the native structures for chemical and biological evaluation.
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